Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.     

Rainfall partitioning through a mixed cedar swamp and associated C and N fluxes in Southern Ontario,Canada

Partitioning of rainfall through a forest canopy into throughfall, stemflow, and canopy interception is a critical process in the water cycle, and the contact of precipitation with vegetated surfaces leads to increased delivery of solutes to the forest floor. This study investigates the rainfall partitioning over a growing season through a temperate, riparian, mixed coniferous‐deciduous cedar swamp, an ecosystem not well studied with respect to this process. Seasonal throughfall, stemflow, and interception were 69.2%, 1.5%, and 29.3% of recorded above‐canopy precipitation, respectively. Event throughfall ranged from a low of 31.5 ± 6.8% for a small 0.8‐mm event to a high of 82.9 ± 2.4% for a large 42.7‐mm event. Rain fluxes of at least 8 mm were needed to generate stemflow from all instrumented trees. Most trees had funnelling ratios <1.0, with an exponential decrease in funnelling ratio with increasing tree size. Despite this, stand‐scale funnelling ratios averaged 2.81 ± 1.73, indicating equivalent depth of water delivered across the swamp floor by stemflow was greater than incident precipitation. Throughfall dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) averaged 26.60 ± 2.96 and 2.02 ± 0.16 mg L^?1, respectively, which were ~11 and three times above‐canopy rain levels. Stemflow DOC averaged 73.33 ± 7.43 mg L^?1, 35 times higher than precipitation, and TDN was 4.45 ± 0.56 mg L^?1, 7.5 times higher than rain. Stemflow DOC concentration was highest from Populus balsamifera and TDN greatest from Thuja occidentalis trees. Although total below‐canopy flux of TDN increased with increasing event size, DOC flux was greatest for events 20–30 mm, suggesting a canopy storage threshold of DOC was readily diluted. In addition to documenting rainfall partitioning in a novel ecosystem, this study demonstrates the excess carbon and nitrogen delivered to riparian swamps, suggesting the assimilative capacity of these zones may be underestimated.     

Calibration of paired watersheds: Utility of moving sums in presence of externalities

Historically, paired watershed studies have been used to quantify the hydrological effects of land use and management practices by concurrently monitoring 2 similar watersheds during calibration (pretreatment) and post‐treatment periods. This study characterizes seasonal water table and flow response to rainfall during the calibration period and tests a change detection technique of moving sums of recursive residuals (MOSUM) to select calibration periods for each control–treatment watershed pair when the regression coefficients for daily water table elevation were most stable to minimize regression model uncertainty. The control and treatment watersheds were 1 watershed of 3–4‐year‐old intensely managed loblolly pine (Pinus taeda L.) with natural understory, 1 watershed of 3–4‐year‐old loblolly pine intercropped with switchgrass (Panicum virgatum), 1 watershed of 14–15‐year‐old thinned loblolly pine with natural understory (control), and 1 watershed of switchgrass only. The study period spanned from 2009 to 2012. Silvicultural operational practices during this period acted as external factors, potentially shifting hydrologic calibration relationships between control and treatment watersheds. MOSUM results indicated significant changes in regression parameters due to silvicultural operations and were used to identify stable relationships for water table elevation. None of the calibration relationships developed using this method were significantly different from the classical calibration relationship based on published historical data. We attribute that to the similarity of historical and 2010–2012 leaf area index on control and treatment watersheds as moderated by the emergent vegetation. Although the MOSUM approach does not eliminate the need for true calibration data or replace the classic paired watershed approach, our results show that it may be an effective alternative approach when true data are unavailable, as it minimizes the impacts of external disturbances other than the treatment of interest.     

Factors controlling the interannual variations of MJO intensity

The interannual variations of intensity of the Madden-Julian Oscillation (MJO) during boreal winter are investigated by using the observed outgoing longwave radiation (OLR) and the reanalysis data of ECMWF and NCEP. The standard deviation of 20-80-day filtered OLR anomaly is used to measure the MJO intensity. The dominant spatial structure of the interannual variability is revealed by an EOF analysis of the MJO intensity field. It is found that the leading mode is associated with eastern Pacific type ENSO, whereas the second mode is related to central Pacific type ENSO. A simple atmospheric model is used to investigate the relative roles of background moisture and wind changes in affecting the overall strength of MJO. The numerical experiments indicate that the background moisture effect is dominant while the background wind change has a minor effect.     

Evaluation of coseismic landslide hazard on the proposed Haast-Hollyford Highway,South Island,New Zealand

Coseismic landsliding presents a major hazard to infrastructure in mountains during large earthquakes. This is particularly true for road networks, as historically coseismic landsliding has resulted in road losses larger than those due to ground shaking. Assessing the exposure of current and planned highway links to coseismic landsliding for future earthquake scenarios is therefore vital for disaster risk reduction. This study presents a method to evaluate the exposure of critical infrastructure to landsliding from scenario earthquakes from an underlying quantitative landslide hazard assessment. The method is applied to a proposed new highway link in South Island, New Zealand, for a scenario Alpine Fault earthquake and compared to the current network. Exposure (the likelihood of a network being affected by one or more landslides) is evaluated from a regional-scale coseismic landslide hazard model and assessed on a relative basis from 0 to 1. The results show that the proposed Haast-Hollyford Highway (HHH) would be highly exposed to coseismic landsliding with at least 30–40?km likely to be badly affected (the Simonin Pass route being the worse affected of the two routes). In the current South Island State Highway network, the HHH would be the link most exposed to landsliding and would increase the total network exposure by 50–70% despite increasing the total road length by just 3%. The present work is intended to provide an effective method to assess coseismic landslide hazard of infrastructure in mountains with seismic hazard, and potentially identify mitigation options and critical network segments.     

Metasomatism and the crystallization of zircon megacrysts in Archaean peridotites from the Lewisian complex,NW Scotland

Zircon megacrysts are locally abundant in 1–40 cm-thick orthopyroxenite veins within peridotite host rocks in the Archaean Lewisian gneiss complex from NW Scotland. The veins formed by metasomatic interaction between the ultramafic host and Si-rich melts are derived from partial melting of the adjacent granulite-facies orthogneisses. The interaction produced abundant orthopyroxene and, within the thicker veins, phlogopite, pargasite and feldspathic bearing assemblages. Two generations of zircon are present with up to 1 cm megacrystic zircon and a later smaller equant population located around the megacryst margins. Patterns of zoning, rare earth element abundance and oxygen isotopic compositions indicate that the megacrysts crystallized from crustal melts, whereas the equant zircon represents new neocryst growth and partial replacement of the megacryst zircon within the ultramafic host. Both zircon types have U–Pb ages of ca. 2464 Ma, broadly contemporaneous with granulite-facies events in the adjacent gneisses. Zircon megacrysts locally form?>?10% of the assemblage and may be associated to zones of localized nucleation or physically concentrated during movement of the siliceous melts. Their unusual size is linked to the suppression of zircon nucleation and increased Zr solubility in the Si-undersaturated melts. The metasomatism between crustal melts and peridotite may represent an analog for processes in the mantle wedge above subducting slabs. As such, the crystallization of abundant zircon in ultramafic host rocks has implications for geochemistry of melts generated in the mantle and the widely reported depletion of high field strength elements in arc magmas.     

The Anglo-Brabant Massif: Persistent but enigmatic palaeo-relief at the heart of western Europe

The surface geology of central England and Belgium obscures a large ‘basement’ massif with a complex history and stronger crust and lithosphere than surrounding regions. The nucleus was forged by subduction-related magmatism at the Gondwana margin in Ediacaran time. Partitioning into a platform, in the English Midlands, and a basin stretching to Belgium, in the east, was already evident in Cambrian/earliest Ordovician time. The accretion of the Monian Composite Terrane during the Penobscotian deformation phase preceded late Tremadocian rifting, and Floian separation, of the Avalonia Terrane from the Gondwana margin. Late Ordovician magmatism in a belt from the Lake District to Belgium records subduction beneath Avalonia of part of the Tornquist Sea. This ‘Western Pacific-style’ oceanic basin closed in latest Ordovician time, uniting Avalonia and Baltica. Closure of the Iapetus Ocean in early Silurian time was soon followed by closure of the Rheic Ocean, recorded by subduction along the southern margin of the massif. The causes of late Caledonian deformation are poorly understood and controversial. Partitioned behaviour of the massif persisted into late Palaeozoic time. Late Devonian and Carboniferous sequences show strong onlap onto the massif, which was little affected by crustal extension. Compressional deformation during the Variscan Orogeny also appears slight, and was focussed in the west where a wedge-shaped mountain foreland uplift was driven by orogenic indentation, splitting the massif from the Welsh Massif along the reactivated Malvern Line. Permian to Mesozoic sequences exhibit persistent but variable degrees of onlap onto the massif.     

淮河流域夏季极端降水频次空间分布的客观分类及其形成机理

本文基于1961～2016年淮河流域四省（江苏、安徽、河南、山东）逐日降水观测资料及全球大气再分析资料,利用K均值聚类、旋转经验正交函数分解对淮河流域夏季极端降水频次分布进行了客观分类,利用统计诊断和数值模拟的手段讨论了其相关环流异常和形成机理。结果表明:（1）淮河流域夏季极端降水频次的空间分布可客观分为以极端降水主要发生在淮河流域33°N以南地区的南部型,主要发生在32°～36°N之间的中部型,和主要发生在34°N以北的北部型这三种分布类型;（2）南部型极端降水频次分布与西北太平洋副热带高压异常偏西偏南有关,西北太平洋异常反气旋北侧的异常气旋性环流使得水汽输送停留在淮河流域南部,导致南部极端降水频次偏多。中部型对应淮河流域受鞍型场环流结构控制,导致中部极端降水频次偏多。北部型极端降水频次分布时,淮河流域处于反气旋性环流异常西南侧,偏南风将水汽输送至淮河流域北部,导致北部极端降水频次偏多;（3）南部型和北部型的极端降水频次分布相关环流异常分别受厄尔尼诺和拉尼娜相关海表温度异常所影响,而中部型极端降水频次分布的相关环流异常是巴伦支海/喀拉海海冰异常在欧亚大陆上空激发的自西北向东南传播的准定常罗斯贝波所导致的。